This should be taken as an indication of topics to be covered
only. There is a possibility that all topics will not be covered.
Remember that this is one-half of a two-semester course. Previous
chapters were covered in the first
semester.
Handouts and web resources for the chapters covered may be found
by following the links below.
|
Chpt
|
Title
|
Handouts
|
|
10
|
Conjugation in Alkadienes and
Allylic Systems
|
Electrophilic
Addition (html)
Diels-Alder
Basics (html), (pdf)
Products with
Chime
Diels-Alder
Stereochemistry (html), (pdf)
Stereochem for the
Lab (#6)
|
|
11
|
Arenes and Aromaticity
|
What Makes it
Aromatic?, (pdf)
Aromatic Molecular
Orbitals, (pdf)
Polycyclic
Aromatic Hydrocarbons, (pdf)
Fullerenes (html)
Estrogenic
Compounds (html) |
|
12
|
Reactions of Arenes: Electrophilic
Aromatic Substitution
|
Electrophilic Aromatic Substitution-Basics
and Orientation
(pdf files)
Reactions at the
Benzylic Position (pdf file)
Friedel-Crafts
reactions (pdf file)
Aromatic
Synthetic Strategy (pdf file)
|
|
13
|
Spectroscopy-General
Helpful
Links
Combined
Problems (WebSpectra)
|
Spectroscopy
Basics (pdf)
Combined
Spectroscopy (pdf)
|
|
13a
|
Mass Spectrometry
|
GCMSApplications
|
|
13b
|
Infrared and Ultraviolet-Visible
Spectroscopy
|
Infrared
Links
Infrared Theory
(pdf)
Infrared
Interpretation
Infrared Decision Tree
Correlation
Table (pdf)
Correlation Bar
Chart (pdf)
UV of
Polyenes (pdf)
|
|
13c
|
Nuclear Magnetic Resonance
Spectroscopy
|
NMR Overview
Carbon NMR
Proton NMR
How to Read NMR (html
or pdf)
|
|
14
|
Organometallic Compounds
|
Acid/Base
chemistry of functional groups
Acid/Base fundamentals (pdf)
|
|
15
|
Alcohols, Diols, and Thiols
|
Alcohol Synthesis (pdf)
|
|
16
|
Ethers, Epoxides and Sulfides
|
Ether
Properties & Formation (pdf file)
Epoxides Formation
and Rxns (pdf file)
|
|
17
|
Aldehydes and Ketones: Nucleophilic
Addition to the Carbonyl Group
|
Carbonyl
Examples
Molecular Orbital
Pictures
Formation of aldehydes
and ketones
Initial reactions of
aldehydes and ketones
Hydrate formation
Formation of acetals and
ketals
Formation of imines and
enamimes
Transamination
Visual pigment formation
and reaction
Formation and synthetic
utility of dithianes
The Wittig reaction
Synthetic examples using
alkynes or Wittig reaction
Reduction and oxidation of
aldehydes or ketones
|
|
18
|
Enols and Enolates
|
|
|
19
|
Carboxylic Acids
|
Formation of Carboxylic
Acids
Dissociation of Acids
(acid/base)
|
|
20
|
Carboxylic Acid Derivatives:
Nucleophilic Acyl Substitution
|
Acid
Derivatives Reactivity
Acid
Derivatives Chemistry Overview
Acid
Derivatives Substitution Examples (pdf file)
|
|
21
|
Ester Enolates
|
|
|
22
|
Amines
|
Basicity of
Amines
Acidity of
Amines
Synthesis of Amines
(pdf file)
|
|
23
|
Aryl Halides
|
|
|
24
|
Phenols
|
|
|
25
|
Carbohydrates
|
|
|
26
|
Acetate-Derived Natural Products
|
|
|
27
|
Amino Acids, Peptides, and
Proteins. Nucleic Acids
|
|
